Diseño, síntesis y caracterización de novedosos catalizadores heterogéneos sólidos a partir de materiales renovables.
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Abstract
Mesoporous siliceous solids have been successfully synthesized from innovative and sustainable methodologies, employing renewable precursors and more environmentally friendly synthesis routes (sol-gel method). The starting materials were obtained by hydrothermal synthesis, using a silicon source extracted from rice husk and glyceryl monostearate as a porogen. These nanostructured materials were prepared with different Al contents by direct incorporation synthesis (Si/Al= 10, 30, 60 and 100) and were characterized by N2 adsorption, SEM-EDS, TEM, NMR, IR-TF and pyridine adsorption coupled to IR-FT spectroscopy. Thus, the highest incorporation of aluminum in the material structure was achieved from an initial molar ratio of Si/Al= 10, hydrothermal treatment for three days and one hour of calcination at 550 °C. This feature led to a high acidity in the designed solids, which makes them attractive catalysts to be applied in industrial reactions of interest driven by acid sites.
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